410096-22-9Relevant academic research and scientific papers
Cyclopalladated complexes with functionalized diphosphines via activation of chelated 1,1-bis(diphenylphosphino) ethene
Teijido, Berta,Fernández, Alberto A.,López-Torres, Margarita,Suárez, Antonio,Vila, José M.,Mosteiro, Roberto,Fernández, Jesús J.
, p. 1304 - 1307 (2008/10/08)
The reaction of 1 with 1,1-bis(diphenylphosphino)ethene (vdpp) gave the mononuclear cyclometalated compound 2. The withdrawing effect of the cyclopalladated moiety suffices to polarize the C=CH2 double bond to afford the addition products 3-8,
