4103-14-4Relevant academic research and scientific papers
The cis-Cyclo-oct-4-enyl Radical is Reluctant to Rearrange
Bloodworth, A. J.,Crich, David,Melvin, T.
, p. 786 - 788 (1987)
The cis-cyclo-oct-4-enyl radical, generated both photochemically and thermally from the O-acyl thiohydroxamate (9) is efficiently trapped by (9), terachloromethane, 1,1-diethylpropanethiol, and oxygen.
Chemistry of the (Z)-Cyclo-oct-4-enyl Radical Including the Preparation of 18O2-Labelled (Z)-Cyclo-oct-4-enyl Hydroperoxide
Bloodworth, A. J.,Crich, David,Melvin, T.
, p. 2957 - 2961 (2007/10/02)
Photolysis of the O-acyl thiohydroxamate (2), precursor to the (Z)-cyclo-oct-4-enyl radical, in the presence of 18O2 and tertiary thiol provides the labelled hydroperoxide (8).The parent (Z)-cyclo-oct-4-enyl radical is shown to undergo transannular cyclization only under relatively forcing conditions.
