410535-69-2Relevant academic research and scientific papers
An enantioselective total synthesis of (-)-stemoamide
Sibi, Mukund P.,Subramanian, Thangaiah
, p. 1211 - 1214 (2004)
An enantioselective synthesis of (-)-stemoamide has been achieved in 14 steps starting from pyroglutamyl alcohol in ca. 7% overall yield. The key steps in the strategy are a conjugate addition of a vinyl copper reagent and a ring closing metathesis (RCM) reaction to form the seven-membered ring.
