41085-77-2Relevant academic research and scientific papers
MECHANISM OF THE ELECTROCHEMICAL REDUCTION OF 2-HALO-5-NITROTHIOPHENES IN DIMETHYLFORMAMIDE
Sosonkin, I. M.,Strogov, G. N.,Ponomareva, T. K.,Domarev, A. N.,Glushkova, A. A.,Freidlin, G. N.
, p. 137 - 140 (1981)
The reduction of 2-bromo-5-nitrothiophene and 2-iodo-5-nitrothiophene in dimethylformamide (DMF) was studied by means of classical and commutated polarography, EPR spectroscopy, a rotating platinum disk electrode with a ring, and preparative electrolysis.It was established that, depending on the nature of the halogen, their anion radicals may undergo further reduction to 2-nitrothiophene anion radicals or decomposition with splitting out of a halide anion and conversion to nitrothienyl radicals, which were identified on the ring electrode.The latter are capable of undergoing dimerization to 2,2'-dinitro-5,5'-dithienyl.The spectra of the anion radicals of 2-nitrothiophene and 2,2'-dinitro-5,5'dithienyl were recorded by means of EPR.A mechanism for the reduction of halonitrothiophenes is proposed.
A convenient catalytic route to symmetrical functionalized bithiophenes
Hassan, Jwanro,Lavenot, Laurence,Gozzi, Christel,Lemaire, Marc
, p. 857 - 858 (2007/10/03)
A series of symmetrical functionalized bithiophenes has been synthesized in good to excellent yields via homocoupling of thiophene halides in the presence of Pd(OAc)2 as a catalyst.
