41097-19-2

Basic information

• Product Name: Phosphonic acid, (4-methylbenzoyl)-, bis(1-methylethyl) ester
• CAS NO: 41097-19-2
• Molecular Formula: C14H21O4P
• Molecular Weight: 284.292
• Mol File: 41097-19-2.mol
• Article Data: 3

Chemical Properties

• CAS DataBase Reference: Phosphonic acid, (4-methylbenzoyl)-, bis(1-methylethyl) ester(CAS DataBase Reference)
• NIST Chemistry Reference: Phosphonic acid, (4-methylbenzoyl)-, bis(1-methylethyl) ester(41097-19-2)
• EPA Substance Registry System: Phosphonic acid, (4-methylbenzoyl)-, bis(1-methylethyl) ester(41097-19-2)

Safety Data

• Hazardous Substances Data: 41097-19-2(Hazardous Substances Data)

Upstream product

• 513-02-0 triisopropyl phosphate 
• 874-60-2 4-methyl-benzoyl chloride 
• 106736-84-9 diisopropyl (+/-)-[hydroxy(4-methylphenyl)methyl]phosphonate 
• 116-17-6 triisopropyl phosphite 

Downstream Products

• 1136222-73-5 diisopropyl (S)-(-)-[hydroxy(4-methylphenyl)methyl]phosphonate 
• 106736-84-9 diisopropyl (+/-)-[hydroxy(4-methylphenyl)methyl]phosphonate 
• 1310408-42-4 C₁₇H₂₇O₅P 

Relevant articles and documents

Synthesis of 2-phosphonoheterocycles via base-promoted 5-endo cyclization

Herein, a synthesis of 2-phosphonodihydrofurans and 2-phosphonodihydropyrroles via 5-endo cyclization of O-and N-propargylated compounds is described. The reaction is promoted by potassium tert-butoxide and allows a fast access to interesting heterocycles which were easily converted into 2-arylated pyrroles under acidic conditions.

Asymmetric hydrogenation of α-keto phosphonates with chiral palladium catalysts

Under atmospheric hydrogen pressure, a catalytic amount of palladium(II) trifluoroacetate and (R)-MeO-BIPHEP in 2,2,2-trifluoroethanol promoted the asymmetric hydrogenation of diisopropyl α-keto phosphonates 1 to afford the corresponding α-hydroxy phospho