4112-08-7Relevant academic research and scientific papers
Visible-light-responsive multielectron redox catalysis of lacunary polyoxometalates induced by substrate coordination to their lacuna
Suzuki, Kosuke,Jeong, Jinu,Yamaguchi, Kazuya,Mizuno, Noritaka
supporting information, p. 144 - 148 (2015/02/19)
We describe herein the efficient visible-light-responsive polyoxometalate-based multielectron photoredox catalysis induced by in situ coordination of alcohols to the lacuna of TBA4H4[γ-SiW10O36] (I, TBA=tetra-n-butylammonium). The coordination of alcohols to the lacuna of I generated a new highest occupied molecular orbital as the electron donor level and enabled the visible-lightresponsive multielectron transfer from alcohols to I, which could be utilized for aerobic alcohol oxidation and onepot synthesis of N-arylimines starting from nitroarenes and primary alcohols.
