41120-00-7Relevant academic research and scientific papers
Silver(I) Isocyanide Complexes: Spectroscopic Features and Reactions with Neutral Ligands
Bell, Andrew,Edwards, Dennis A.
, p. 1317 - 1322 (2007/10/02)
The silver(I) isocyanide complexes ClO4 (R = Me, cyclo-C6H11, or But) and ClO4 have been prepared, their i.r., Raman, 1H and 13C n.m.r. spectra recorded, and assignments proposed.Particular emphasis has been placed on an assigment of the vibrational spectrum of ClO4.Some reactions of ClO4 and t)4>ClO4 with neutral Group 5 donor ligands have been examined.Complete isocyanide displacement leads to the complexes ClO4 .The mixed-ligand complexes ClO4 (R = C6H11 or But; bipy = 2,2'-bipyridyl), ClO4 (py = pyridine) and ClO4 L3 = (Ph2PCH2)3CMe, L = P(OMe)3> have also been prepared.The complexes involving nitrogen donors appear to contain three-co-ordinate silver(I) whereas those involving phosphorus donors contain four-co-ordinate silver(I).
