411208-69-0

Basic information

• Product Name: (σ-N,σ-N'-1,4-di(4-methoxyphenyl)-1,4-diaza-1,3-butadiene)(η(2)-(E)-dimethylbut-2-ene-1,4-dioate)platinum(0)
• CAS NO: 411208-69-0
• Molecular Weight: 607.522
• Mol File: 411208-69-0.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: (σ-N,σ-N'-1,4-di(4-methoxyphenyl)-1,4-diaza-1,3-butadiene)(η(2)-(E)-dimethylbut-2-ene-1,4-dioate)platinum(0)(CAS DataBase Reference)
• NIST Chemistry Reference: (σ-N,σ-N'-1,4-di(4-methoxyphenyl)-1,4-diaza-1,3-butadiene)(η(2)-(E)-dimethylbut-2-ene-1,4-dioate)platinum(0)(411208-69-0)
• EPA Substance Registry System: (σ-N,σ-N'-1,4-di(4-methoxyphenyl)-1,4-diaza-1,3-butadiene)(η(2)-(E)-dimethylbut-2-ene-1,4-dioate)platinum(0)(411208-69-0)

Safety Data

• Hazardous Substances Data: 411208-69-0(Hazardous Substances Data)

Upstream product

• 12130-66-4 bis(cycloocta-1,5-diene)platinum⁽⁰⁾ 
• 24978-42-5 1,4-bis(4'-methoxyphenyl)-1,4-diazabuta-1,3-diene 
• 23055-10-9 1,4-dimethyl but-2-enedioate 

Relevant articles and documents

Synthesis of new (σ2-N,N′-diazadiene)(η2-alkene) platinum(0) compounds

Novel, thermally stable, dark-red to orange Pt0(σ2-N,N′-diazadiene) (η2-alkene) compounds have been synthesized in good yields from Pt0(COD)2 or Pt0(NBE)3, by stepwise substitution of the respective dienes or alkenes by an electron-poor alkene (dimethyl fumarate, maleic anhydride or fumaronitrile), followed by the appropriate diazadiene ligand in dry diethyl ether at 20°C (diazadiene = various N,N′-disubstitued-1,4-diaza-1,3-dienes). The complex Pt(DBA)2 is less suited as a precursor for the synthesis of Pt0(σ2-N,N′-diazadiene) (η2-alkene) compounds. These zerovalent Pt(diazadiene)(η2-alkene) compounds constitute a useful category of starting materials for synthetic organoplatinum chemistry and catalysis.