41145-51-1Relevant articles and documents
Ruthenium-catalyzed direct amination of alcohols with tertiary amines
Luo, Jiaying,Wu, Mingyue,Xiao, Fuhong,Deng, Guojun
experimental part, p. 2706 - 2709 (2011/06/19)
A highly selective phosphine-based ruthenium catalyst system efficiently catalyzes the direct amination of alcohols with aliphatic tertiary amines, yielding unsymmetric tertiary amines in yields up to 87%. Ligand and solvent both affect the reaction yields significantly. The reaction can be performed with a wide variety of functionalities.
Joint Synthesis of Tertiary Unsymmetrical and Symmetrical Aliphatic Amines
Kozlov,Tereshko,Basalaeva,Tarasevich
, p. 1095 - 1098 (2007/10/03)
Tertiary unsymmetrical and symmetrical aliphatic amines were prepared by reaction of higher (C8-C16) and lower (C2-C4) aliphatic alcohols with nitriles containing the same number of carbon atoms as the lower aliphatic alcohols. Reaction conditions ensuring nearly quantitative yields of tertiary amines were determined.