412015-10-2Relevant academic research and scientific papers
Syntheses of (-)-(7S)- and (+)-(7R)-K252a dimers
Tamaki, Kazuhiko,Huntsman, Elliott W.D,Petsch, Dejah T,Wood, John L
, p. 379 - 382 (2002)
This letter describes syntheses of (-)-(7S)-and (+)-(7R)-K252a dimers wherein a convergent bis-indole-N-glycosidic coupling step was used for the resolution of the C(7) substituted (±)-aglycon. Dimerization of the derived monomers was achieved via olefin methathesis.
