412021-24-0

Basic information

• Product Name: (1R,2R)-2-Nitromethyl-1-phenyl-pentane-1-sulfonic acid (3aR,5R,6R,6aR)-5-((R)-2,2-dimethyl-[1,3]dioxolan-4-yl)-2,2-dimethyl-tetrahydro-furo[2,3-d][1,3]dioxol-6-yl ester
• CAS NO: 412021-24-0
• Molecular Weight: 529.609
• Mol File: 412021-24-0.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: (1R,2R)-2-Nitromethyl-1-phenyl-pentane-1-sulfonic acid (3aR,5R,6R,6aR)-5-((R)-2,2-dimethyl-[1,3]dioxolan-4-yl)-2,2-dimethyl-tetrahydro-furo[2,3-d][1,3]dioxol-6-yl ester(CAS DataBase Reference)
• NIST Chemistry Reference: (1R,2R)-2-Nitromethyl-1-phenyl-pentane-1-sulfonic acid (3aR,5R,6R,6aR)-5-((R)-2,2-dimethyl-[1,3]dioxolan-4-yl)-2,2-dimethyl-tetrahydro-furo[2,3-d][1,3]dioxol-6-yl ester(412021-24-0)
• EPA Substance Registry System: (1R,2R)-2-Nitromethyl-1-phenyl-pentane-1-sulfonic acid (3aR,5R,6R,6aR)-5-((R)-2,2-dimethyl-[1,3]dioxolan-4-yl)-2,2-dimethyl-tetrahydro-furo[2,3-d][1,3]dioxol-6-yl ester(412021-24-0)

Safety Data

• Hazardous Substances Data: 412021-24-0(Hazardous Substances Data)

Upstream product

• 3156-72-7 (1E)-1-nitropent-1-ene 
• 412021-12-6 Phenyl-methanesulfonic acid (3aR,5R,6R,6aR)-5-((R)-2,2-dimethyl-[1,3]dioxolan-4-yl)-2,2-dimethyl-tetrahydro-furo[2,3-d][1,3]dioxol-6-yl ester 

Relevant articles and documents

Asymmetric Michael addition of chiral lithiated sulfonates to nitroalkenes: Diastereo- and enantioselective synthesis of α,β-disubstituted γ-nitro and β-alkoxycarbonyl methyl sulfonates

The diastereoselective Michael addition of lithiated enantiopure sulfonates to nitroalkenes is described. High asymmetric inductions were obtained by using 1,2:5,6-di-O-isopropylidene-α-D-allofuranose as a cheap and easily available chiral auxiliary. Race