412303-79-8

Upstream product

• 939-97-9 4-tert-Butylbenzaldehyde 
• 1571-08-0 methyl 4-formylbenzoate 
• 39895-55-1 4-(1,1-dimethylethyl)-benzenemethanamine 

Downstream Products

• 412303-83-4 ((CH₂CH₂O)3C₆H₄O)2*(CH₃)3CC₆H₄CH₂NH₂CH₂C₆H₄C(O)NHC₅H₄N⁽¹⁺⁾*CF₃COO^(1-)=C₂₄H₃₂O₈C₂₄H₂₈N₃OC₂F₃O₂ 
• 477884-48-3 (4-tert-butyl-benzyl)-[4-(pyridin-4-ylcarbamoyl)-benzyl]-carbamic acid tert-butyl ester 
• 412303-80-1 4-{[tert-butoxycarbonyl-(4-tert-butyl-benzyl)-amino]-methyl}-benzoic acid 
• 412303-81-2 4-[(4-tert-butyl-benzylamino)-methyl]-N-pyridin-4-yl-benzamide 

Relevant academic research and scientific papers

A high-yielding and convenient synthesis of rotaxane based on an ester forming capping methodology

An efficient method for preparation of rotaxanes, involving hydrogen bonding guided self-assembly and diaryldiazoalkanes ester forming end-capping of pseudorotaxanes, is described. The end-capping reactions proceed under mild conditions and furnish the ex

Preparation of porphyrin-stoppered rotaxane aiming at immobilization on substrate

The porphyrin-stoppered rotaxane was prepared from dibenzo-24-crown-8 (DB24C8) and the secondary ammonium ion derivative end-capped by the axial coordination of rhodium(III) tetra-(3,5-di-tert-butylphenyl) porphyrin [TBPP Rh(III) C1]. This rotaxane molecule was designed aiming at the immobilization on a substrate and the analysis of the physicochemical properties as a single molecule.

Triphenylphosphonium-stoppered [2]rotaxanes

(equation presented) The template-directed syntheses of two [2]rotaxanes, one carrying one and the other two triphenylphosphonium stoppers, have been achieved using a threading-followed-by-stoppering approach. Either one or two benzylic bromide functions-