412346-29-3

Basic information

• Product Name: Oxiranemethanol, 3,3-dimethyl--alpha--(1-methylethenyl)- (9CI)
• Synonyms: Oxiranemethanol, 3,3-dimethyl--alpha--(1-methylethenyl)- (9CI)
• CAS NO: 412346-29-3
• Molecular Formula: C8H14O2
• Molecular Weight: 0
• Mol File: 412346-29-3.mol

Chemical Properties

• Appearance: /
• CAS DataBase Reference: Oxiranemethanol, 3,3-dimethyl--alpha--(1-methylethenyl)- (9CI)(CAS DataBase Reference)
• NIST Chemistry Reference: Oxiranemethanol, 3,3-dimethyl--alpha--(1-methylethenyl)- (9CI)(412346-29-3)
• EPA Substance Registry System: Oxiranemethanol, 3,3-dimethyl--alpha--(1-methylethenyl)- (9CI)(412346-29-3)

Safety Data

• Hazardous Substances Data: 412346-29-3(Hazardous Substances Data)

Upstream product

• 764-13-6 2,5-Dimethyl-2,4-hexadiene 
• 94098-84-7 2,5-dimethyl-3-hydroperoxy-1,4-hexadiene 

Downstream Products

• 22520-37-2 dl-2,5-dimethylhexane-3,4-diol 
• 4723-10-8 racem. 2,5-dimethyl-hexa-1,5-diene-3,4-diol 

Relevant articles and documents

REGIO-CONTROLLED FUNCTIONALIZATION OF 2,5-DIMETHYL-2,4-HEXADIENE INTO EPOXY ALCOHOLS BY PHOTOOXYGENATION IN THE PRESENCE OF TITANIUM(IV) OR VANADIUM(V)

Using Ti(OiPr)4 as oxygen transfer catalyst, the diene 1 afforded exclusively the epoxy alcohol 1c, but VO(acac)2 gave exclusively the isomerized epoxy alcohol 2c during its ene reaction with singlet oxygen.

A CONVENIENT "ONE-POT" SYNTHESIS OF EPOXY ALCOHOLS VIA PHOTOOXYGENATION OF OLEFINS IN THE PRESENCE OF TITANIUM(IV) CATALYST

The ene reaction of singlet oxygen with alkenes in the presence of titanium alkoxides was employed to prepare epoxy alcohols in high diastereoselectivity; enantioselectivity could be achieved by use of diethyl tartrate as chiral auxiliary.