41242-29-9Relevant academic research and scientific papers
Direct conversion of azides to carbamates and sulfonamides using Fe/NH4Cl: Effect of sonication
Chandrasekhar,Narsihmulu
, p. 7969 - 7972 (2000)
A simple, direct and effective conversion of azides to carbamates and sulfonamides is achieved using Fe/NH4Cl in methanol. The influence of sonication and direct application in solution phase combinatorial chemistry are also studied by developing a 6x4 matrix library. (C) 2000 Elsevier Science Ltd.
Facile double-lithiation of a transient urea: Vicarious ortho -metalation of aniline derivatives
Houlden, Chris E.,Lloyd-Jones, Guy C.,Booker-Milburn, Kevin I.
supporting information; experimental part, p. 3090 - 3092 (2010/09/05)
A convenient one-pot method for the conversion of phenylisocyanate into ortho-functionalized aniline derivatives has been developed. The reaction proceeds via the selective ortho-metalation of a transient labile urea, which can be considered as a synthetic equivalent of 2-lithio-phenylisocyanate, a highly improbable intermediate.
A Short Efficient Route to Acronycine and Other Acridones
Horne, Stephen,Rodrigo, Russell
, p. 1046 - 1048 (2007/10/02)
A Fries type rearrangement of N-tosyl-o-iodobenzanilides, triggered by lithium-iodine exchange at low temperature is the key step in a general, regiospecific synthesis of acridones.
