412911-45-6Relevant articles and documents
Synthesis and structure of the first stable phosphabismuthene
Sasamori, Takahiro,Takeda, Nobuhiro,Fujio, Mizue,Kimura, Masahiro,Nagase, Shigeru,Tokitoh, Norihiro
, p. 139 - 141 (2002)
The exceedingly different size of p orbitals is overcome in the novel doubly bonded system between phosphorus and bismuth atoms that occurs in the first stable phosphabismuthene 1. Compound 1 was obtained from the condesation reaction of Mes*PH2 with an overcrowed dibromobismuthane by using 1,8-diazabicyclo[5.4.0]undec-7-ene (DBU) as a base (see scheme).