41326-64-1Relevant articles and documents
Stereochemistry of Dehydrogenation of 1,4-cyclohexadiene with 2,3-dichloro-5,6-dicyano-p-benzoquinone
Mueller, Paul,Joly, Daniel,Mermoud, Francois
, p. 105 - 112 (2007/10/02)
cis- and trans-(3,6-D2)-1,4-cyclohexadienes 1a and 1b have been synthesized from cis-3,4-dichlorocyclobutene (5).Aromatization to benzene with DDQ is cis-stereospecific with an uncertainty of 5percent.This results is discussed in relation to concerted or stepwise mechanisms for aromatization of 1,4-dihydroaromatics with 2,3-dichloro-5,6-dicyano-p-benzoquinone (DDQ).