41345-58-8Relevant academic research and scientific papers
Natural acetylenes. Part XL. Syntheses of polyacetylenic C18 and C16 esters with 9-Ene-12,14-diyne unsaturation, and their labelling
Fallis, Alexander G.,Hearn, Milton T. W.,Jones, Ewart R. H.,Thaller, Viktor,Turner, John L.
, p. 743 - 749 (1973)
The esters R[C≡C]2·CH2·CH= CH·[CH2]7·CO2Me{R=Me[CH 2]2, MeC≡C, cis- or trans-MeCH=CH, trans-HO·CH2·CH=CH, HO·CH 2·C≡C, cis- or trans-MeO2C·CH=CH, MeO2C·C≡C, (EtO)2CH, OHC, or H 2N·OC} were prepared from the Wittig salt Me 3Si·C=C·CH2·CH2· P+Ph3|- via |C≡C·CH2·CH= CH·[CH2]7·CO2Me; several were specifically labelled [at C(9), C(17), and C(18)]. The Wittig salt offers a general route to 1-ene-4,6-diyne and more highly unsaturated skipped en-yne systems.
