41370-29-0Relevant articles and documents
Pheromone Synthesis, CXV. - Synthesis of (Z)-2-Ochtoden-1-ol, (E)-2-Ochtoden-1-al, and (Z)-2-Ochtoden-1-al, the Pheromone Components of the Boll Weevil (Anthonomus grandis)
Mori, Kenji,Itou, Masamichi
, p. 969 - 974 (2007/10/02)
The synthesis of geometrically pure (Z)-2-ochtoden-1-ol (1), (E)-2-ochtoden-1-al (2), and (Z)-2-ochtoden-1-al (3) was achieved starting from myrcene.
HIGHLY STEROSELECTIVE SYNTHESIS OF EXOCYCLIC ALKENES VIA CYCLIALKYLATION
Negishi, Ei-ichi,Zhang, Yantao,Bagheri, Vahid
, p. 5793 - 5796 (2007/10/02)
Treatment of stereodefined ω-halo-2-iodoalkene derivatives (1), prepared via stereoselective addition reactions of alkynes, with either n-BuLi (1 equiv) or t-BuLi (2 equiv) can produce exocyclic alkenes whose isomeric purity is essentially 100percent.
NEW OCHTODANE SYNTHESES FROM MYRCENE
Masaki, Yukio,Hashimoto, Kinji,Sakuma, Kazuhiko,Kaji, Kenji
, p. 1481 - 1484 (2007/10/02)
The ochtodane skeleton is formed stereoselectively from myrcene via acid-catalyzed cyclization of the benzenesulfenyl chloride adduct and the epoxide in a biogenetic type fashion.Its application to the syntheses of two ochtodane-type monoterpenes, an aldehyde component of the boll weevil pheromone and a diol found in the red alga Ochtodes crockeri, is reported.