41370-29-0Relevant articles and documents
Pheromone Synthesis, CXV. - Synthesis of (Z)-2-Ochtoden-1-ol, (E)-2-Ochtoden-1-al, and (Z)-2-Ochtoden-1-al, the Pheromone Components of the Boll Weevil (Anthonomus grandis)
Mori, Kenji,Itou, Masamichi
, p. 969 - 974 (2007/10/02)
The synthesis of geometrically pure (Z)-2-ochtoden-1-ol (1), (E)-2-ochtoden-1-al (2), and (Z)-2-ochtoden-1-al (3) was achieved starting from myrcene.
THE STEREOSPECIFIC FORMATION OF AN EXOCYCLIC ALKENE BY A CONSECUTIVE RADICAL CYCLIZATION-ELEIMINATION
Harris, Francis L.,Weiler, Larry
, p. 2941 - 2944 (2007/10/02)
The iodovinylstannanes 4 and 5 were prepared by the conjugate addition of the tri-n-butyltin moiety to a substituted propiolic ester.Compounds 4 and 5 underwent a radical cyclization-elimination reaction to stereospecifically generate an exocyclic alkene.
NEW OCHTODANE SYNTHESES FROM MYRCENE
Masaki, Yukio,Hashimoto, Kinji,Sakuma, Kazuhiko,Kaji, Kenji
, p. 1481 - 1484 (2007/10/02)
The ochtodane skeleton is formed stereoselectively from myrcene via acid-catalyzed cyclization of the benzenesulfenyl chloride adduct and the epoxide in a biogenetic type fashion.Its application to the syntheses of two ochtodane-type monoterpenes, an aldehyde component of the boll weevil pheromone and a diol found in the red alga Ochtodes crockeri, is reported.