41403-44-5Relevant academic research and scientific papers
An efficient synthetic approach to substituted trisphenols (phloroglucide analogues) using tungstosilicic acid in water
Fareghi-Alamdari, Reza,Khalafi-Nezhad, Ali,Zekri, Negar
, p. 887 - 892 (2014)
Tungstosilicic acid was found to be an efficient catalyst for the synthesis of trisphenols using the reaction of 2,6-bis(hydroxymethyl)phenols with phenols in an aqueous medium. The catalytic reactivity of tungstosilicic acid in boiling water was examined with a series of substrates, demonstrating that this catalyst is reactive in the presence of a variety of functionalities. Georg Thieme Verlag Stuttgart. New York.
Solvent-free synthesis of trisphenols as starting precursors for the synthesis of calix[4]arenes using sulfonated multi-walled carbon nanotubes
Fareghi-Alamdari, Reza,Golestanzadeh, Mohsen,Zekri, Negar
, p. 3400 - 3412 (2016/05/09)
The condensation of phenol derivatives (12 substrates) with 2,6-bis(hydroxymethyl)phenols (BMP) (6 examples) is reported using sulfonated multi-walled carbon nanotubes (SO3H@MWCNTs) under solvent-free conditions as starting precursors for the synthesis of macrocyclic molecules of calix[4]arenes. The new protocol provides a series of trisphenol derivatives (21 examples) in high yields (up to 94%) and relatively short reaction times (15-120 min). Also, direct synthesis of calix[4]arenes from different trisphenols by use of the catalyst was reported (5 examples). Furthermore, the synthesized calix[4]arene was obtained using a one-pot method from simple and easily available starting materials such as p-cresol for the synthesis of 5,11,17,23-tetramethylcalix[4]arene-25,26,27,28-tetraol. Also, in this process SO3H@MWCNTs can be reused for seven runs with almost consistent efficiency and can be recovered by easy filtration.
Kinetics of the Bromination of Phenols and Oligonuclear Phenolic Compounds, V. Trinuclear Compounds with the Reacting Unit in the Middle
Boehmer, Volker,Stotz, Diethard,Beismann, Klaus,Vogt, Walter
, p. 65 - 78 (2007/10/02)
The kinetics of the bromination of six differently substituted 2,6-bis(hydroxybenzyl)phenols having only one reactive para position at the phenolic unit in the middle of the molecule were studied in acetic acid at 22 deg C.The reaction rate decreases if i
