41422-91-7Relevant academic research and scientific papers
THE REARRANGEMENT OF 1-NAPHTHYLPHENYLMETHYLSILANE
Becker, Barbara,Herman, Aleksander,Wojnowski, Wieslaw
, p. 293 - 298 (1980)
1-Naphthylphenylmethylsilane has been shown to undergo rearrangement to the 2-isomer when treated with HI in benzene or ether-benzene; protodesilylation also occurs.The rearrangement also takes place when 1-naphthylphenylmethylsilane is heated at 210-220 deg C.
Sila-condensed ring derivative and use and electroluminescent devices thereof
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Paragraph 0079; 0080; 0081, (2018/08/04)
The invention belongs to the technical field of application of photoelectric materials, and in particular relates to a sila-condensed ring derivative and use and electroluminescent devices thereof. Electronic transmission materials with high electron mobility characteristics are formed by bonding different aromatic groups at different sites of the sila-condensed ring derivative with a silicon-fused ring as a core or changing bridging structures. A Strong covalent bond is formed between silicon and a halogen by use of the sila-condensed ring derivative as an electron transport layer, and has astrong electron-drawing effect. The sila-seven membered ring can retain the characteristics of an aromatic ring, meanwhile a non-planar structure formed by sp3 hybridization of the silicon can effectively reduce the entire molecular plane accumulation, the sila-condensed ring derivative has a high triplet state, triplet exciton pass-back can be avoided, and the sila-condensed ring derivative is suitable for fluorescence emitting and phosphorescent light emitting systems.
