414876-38-3Relevant academic research and scientific papers
Gas-phase nucleophilic aromatic substitution between piperazine and halobenzyl cations: Reactivity of the methylene arenium form of benzyl cations
Chai, Yunfeng,Jiang, Kezhi,Sun, Cuirong,Pan, Yuanjiang
, p. 10820 - 10824 (2011)
Methylene arenium involved in SNAr: The gas-phase nucleophilic aromatic substitution reactions of halobenzyl cations with piperazine through a cationic σ complex were studied using ESI mass spectrometry. This study demonstrates that the methylene arenium form of halobenzyl cations exhibits nucleophilic substitution reactivity at the phenyl ring (see scheme). Copyright
