41563-68-2Relevant academic research and scientific papers
Structural elucidation of an oxidation product of sedimentary porphyrins by one-pot synthesis of 3-methylphthalimide
Nomoto,Kozono,Mita,Shimoyama
, p. 1975 - 1976 (2007/10/03)
One-pot synthesis of 3-methylphthalimide was achieved from 1,2,3-trimethylbenzene. The starting compound was oxidized in two steps to produce methylphthalic acids. The o-isomer was converted into its anhydride, which was subjected to thermal reaction with urea to form 3-methylphthalimide. The product was identical with the reported oxidation product of sedimentary porphyrins.
SYNTHESE PHOTOCHIMIQUE D'HYDROCARBURES POLYCYCLIQUES AROMATIQUES ET ETUDE EN RMN-1H DES PROTONS DE BAIE. EFFECTS DE SOLVANT SPECIFIQUES ET EFFECTS NUCLEAIRES OVERHAUSER.
Brison, Jean,Bakker, Claude de,Defay, Nicole,Geerts-Evrard, France,Marchant, Marie-Jeanne,Martin, Richard H.
, p. 901 - 912 (2007/10/02)
"Photochemical synthesis of polycyclic aromatic hydrocarbons and NMR-1H study of bay protons.Specific solvent effects and nuclear Overhauser effects".Dinaphthoanthracene (4a),9-bromo-dinaphthoanthracene (4b), 9-methyldinaphthoanthracene (4c), benzonaphthochrysene (7), benzonaphthoanthracene (3), naphthochrysene (9) and dibenzonaphthochrysene (12) have been synthesized by the photocyclodehydrogenation of 1,2-diarylethylenes (5,8) and bis (arylvinyl)arenes (6,10).The NMR study has been mainly focused on the bay protons involved in specific solvent effects Table 4) and nuclear Overhauser effects (Table 5).
