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Usage

Uses

Used in Surface Science and Nanotechnology:
1,3-Benzenedimethanethiol is used as an adsorbate for gold surfaces in surface science and nanotechnology applications. Its interaction with the Au surface is crucial for understanding the fundamental properties of metal-organic interfaces and can be utilized in the development of novel sensors, catalysts, and electronic devices.
Used in Analytical Chemistry:
In analytical chemistry, 1,3-benzenedimethanethiol is employed as a probe molecule for studying the surface properties of gold nanoparticles and thin films. Its adsorption behavior provides insights into the surface chemistry and reactivity of gold surfaces, which can be applied to improve the sensitivity and selectivity of analytical methods.
Used in Material Science:
1,3-Benzenedimethanethiol can be used as a component in the synthesis of new materials with tailored properties. Its interaction with gold surfaces can be exploited to create self-assembled monolayers or multilayers, which can be applied in various fields such as corrosion protection, lubrication, and molecular electronics.
Used in Pharmaceutical Research:
Although not explicitly mentioned in the provided materials, 1,3-benzenedimethanethiol may have potential applications in the pharmaceutical industry due to its sulfur-containing structure. It could be used as a building block for the synthesis of new drugs or as a modifier to improve the solubility, stability, or bioavailability of existing pharmaceutical compounds.

InChI:InChI=1/C8H10S2/c9-5-7-2-1-3-8(4-7)6-10/h1-4,9-10H,5-6H2

Upstream product

• 626-18-6 1,3-dimethanol benzene 
• 101822-22-4 1,3-Bis(isothiouroniummethyl)benzene hydrobromide 
• 1459-93-4 dimethyl Isophthalate 
• 626-15-3 1,3-bis-(bromomethyl)benzene 
• 70606-45-0 1,3-bis(t-butylthiomethyl)benzene 
• 626-16-4 3-(chloromethyl)benzyl chloride 

Downstream Products

• 115521-05-6 {6-[3-(6-Hydroxymethyl-pyridin-2-ylmethylsulfanylmethyl)-benzylsulfanylmethyl]-pyridin-2-yl}-methanol 
• 261155-93-5 1-mercaptomethyl-3-(4-methoxycarbonyl-2-thiabutyl)-benzene 
• 848640-72-2 2-(2-{2-[2-(2-{3-[2-(2-{2-[2-(2-hydroxy-ethoxy)-ethoxy]-phenoxy}-ethoxy)-ethylsulfanylmethyl]-benzylsulfanyl}-ethoxy)-ethoxy]-phenoxy}-ethoxy)-ethanol 
• 848640-73-3 C₄₄H₆₆O₁₄S₂ 
• 871239-49-5 C₄₆H₄₂N₄O₄S₂ 
• 261155-94-6 1-(4-carboxy-2-thiabutyl)-3-(4-methoxycarbonyl-2-thiabutyl)-benzene 
• 261155-95-7 1-(4-succinimidoxycarbonyl-2-thiabutyl)-3-(4-methoxycarbonyl-2-thiabutyl)-benzene 
• 261155-91-3 5-[3-(4-methoxycarbonyl-2-thiabutyl)-phenyl]-4-pentanecarboxamidoethyl (α-D-galactopyranosyl)-(1->4)-(β-D-galactopyranosyl)-(1->4)-β-D-glucopyranoside 
• 115521-06-7 Methanesulfonic acid 6-[3-(6-methanesulfonyloxymethyl-pyridin-2-ylmethylsulfanylmethyl)-benzylsulfanylmethyl]-pyridin-2-ylmethyl ester 

Relevant academic research and scientific papers

POLYTHIOL COMPOSITION AND METHOD FOR PRODUCING SAME

The present invention provides a polythiol composition containing, as the main component, a polythiol compound (a) having two or more mercapto groups, and containing 0.5% by mass or less of a nitrogen-containing compound (b) in which at least one mercapto group in the polythiol compound (a) is substituted with a group represented by formula (1).

A Modular Synthesis of Multidentate S-, N- and O-Containing Meta- and Paracyclophanes

The development of a modular approach to macrocycle assembly has enabled the synthesis of a library of pyridine-based macrocycles possessing multiple donor sites where chirality was readily introduced from (R)- or (S)-alanine, a representative amino acid. The facile, regioselective, nucleophilic ring opening of aziridines by dithiols enabled the synthesis of thioether-based linkers which on subsequent alkylation provided access to optically pure macrocycles. A modular approach to macrocyclic assembly has enabled the synthesis of a library of macrocycles possessing multiple donor sites where chirality was readily introduced from (S)-alanine. Key to this approach was the facile, regioselective, nucleophilic ring opening of aziridines by dithiols followed by macrocylisation under conditions of high dilution.

A convenient method for regeneration of free thiol from a tert-butyl thioether

When dimethylmethylthiosulfonium triflate (DMTST) is added to a tert-butyl-protected thiol (RSt-Bu), the unsymmetrical disulfide RSSMe is formed. At this point the free thiol (RSH) can be obtained by the addition of trimethylphosphine and water. Most byproducts are small organic molecules that are easily removed. Georg Thieme Verlag Stuttgart.

Concave Reagents, 7. Concave Benzoic Acids

Based on m-terphenyl units, concave benzoic acids 11a and 12a were prepared via the 2,6-diarylbenzoic acid 7a.Bromination of 7a with NBS gave 9, and cyclization of 9 with dithiols 10 led to the bimacrocyclic concave acids 11a and 12a.Their relative acidit

THE SYNTHESIS AND CHARACTERIZATION OF SOME NEW THIOETHER-IMIDAZOLE CONTAINING LIGANDS.

Procedures are described involving a convenient condensation of 4(5)-hydroxymethylimidazole or 5-methyl-4-hydroxymethylimidazole with several thiols.The main step, the condensation reaction in refluxing acetic acid, is essentially the same for all ligands