415683-81-7Relevant academic research and scientific papers
Methine (CH) transfer via a chlorine atom abstraction/benzene-elimination strategy: Molybdenum methylidyne synthesis and elaboration to a phosphaisocyanide complex
Agapie, Theodor,Diaconescu, Paula L.,Cummins, Christopher C.
, p. 2412 - 2413 (2002)
Methine (CH) transfer to an open coordination site was achieved in one pot by titanium(III) abstraction of Cl from 7-chloronorbornadiene, radical capture by Mo, and benzene extrusion. This efficient Mo methylidyne synthesis permitted elaboration to an ani
An isolable and monomeric phosphorus radical that is resonance-stabilized by the vanadium(IV/V) redox couple
Agarwal, Paresh,Piro, Nicholas A.,Meyer, Karsten,Mueller, Peter,Cummins, Christopher C.
, p. 3111 - 3114 (2008/03/11)
Aiding and abetting a wanted radical: The neutral phosphorus radical [ ?P{NV[N(Np)Ar]3}2] (Np = neopentyl, Ar = 3,5-Me2C6H3) exists as a monomer in the solid state and is resonance-stabilized by two nitridovanadium trisanilide metalloligands through the VIv/Vv redox couple (see EPR trace and calculated SOMO of [?P{NV[N(Me)Ph]3} 2]). The compound undergoes radical reactions at its phosphorus center to form diamagnetic compounds. (Figure Presented).
Radical scission of symmetrical 1,4-dicarbonyl compounds: C-C bond cleavage with titanium(IV) enolate formation and related reactions
Agapie, Theodor,Diaconescu, Paula L.,Mindiola, Daniel J.,Cummins, Christopher C.
, p. 1329 - 1340 (2008/10/08)
Reaction of Ti(NRAr1)3 (1, R = C(CH3)3, Ar1 = 3,5-C6H3Me2) with 0.5 equiv of symmetrical 1,4-diketones (ArCOCH2)2 (Ar = p-Tol or p-MeOC6/su
