415688-70-9Relevant academic research and scientific papers
Synthesis, in silico studies and in vitro evaluation for antioxidant and antibacterial properties of diarylmethylamines: A novel class of structurally simple and highly potent pharmacophore
Mahato, Sujit,Singh, Anuma,Rangan, Latha,Jana, Chandan K.
, p. 202 - 209 (2016/05/24)
A series of novel diarylmethylamines were synthesized via simple three component condensation reaction. In vitro antibacterial activity of the synthesized compounds was assessed against Gram-positive and Gram-negative bacteria. Compound 1f containing phen
Divergent reaction: Metal & oxidant free direct C-H aryloxylation and hydride free formal reductive N-benzylation of N-heterocycles
Mahato, Sujit,Haque, Md Ashraful,Dwari, Soumita,Jana, Chandan K.
, p. 46214 - 46217 (2015/02/19)
Metal, oxidant and other additive-free novel methods for direct C-H aryloxylation of aliphatic amines are developed. In the presence of excess amine, the course of the reaction was diverted, producing various arylmethylamines via hydride-free formal reductive amination. Involvement of a quinone methide intermediate was revealed from mechanistic studies. This journal is
Imidotungsten(vi) complexes with chelating amino and imino phenolates
Haenninen, Mikko M.,Sillanpaeae, Reijo,Kivelae, Henri,Lehtonen, Ari
experimental part, p. 2868 - 2874 (2011/05/14)
The reaction of WOCl4 with 2,4-di-tert-butyl-6-((isopropylamino) methyl)phenol followed by the reaction with phenyl isocyanate leads to the formation of imidotungsten(vi) complex [W(NPh)Cl3(OC 6H3(CH2NH-i-Pr)-2-t-Bu2-4,6)] 4 with a chelating aminophenolate ligand. When the same procedure was applied using aminophenols with bulkier substituents in the amino group, the final product was an unexpected Schiff-base complex [W(NPh)Cl3(OC6H 3(CHNPh)-2-t-Bu2-4,6)] 5, where the ligand is derived from 2,4-di-tert-butyl-6-((phenylimino)methyl)phenol. Complex 5 is also formed in the thermal degradation of 4. On the whole, 5 appears to be formed by a disproportionation of intermediate compounds, which are analogous to complex 4. The solid-state structures of 4 and 5 have been determined by X-ray crystallography whereas the solution structures were studied by 1H and 13C NMR. The Royal Society of Chemistry 2011.
Synthesis, characterization and catalytic activity of magnesium and zinc aminophenoxide complexes: Catalysts for ring-opening polymerization of l-lactide
Chuang, Hui-Ju,Weng, Shi-Feng,Chang, Chia-Chih,Lin, Chu-Chieh,Chen, Hsuan-Ying
experimental part, p. 9601 - 9607 (2011/11/13)
A series of novel magnesium and zinc aminophenoxide complexes were successfully synthesized and one zinc complex was characterized by X-ray crystallography. They were also investigated as initiators for the ring opening polymerization of l-lactide. The co
Monocyclopentadienyl phenoxy-imine and phenoxy-amine complexes of titanium and zirconium and their application as catalysts for 1-alkene polymerisation
Bott, Robyn K.J.,Hughes, David L.,Schormann, Mark,Bochmann, Manfred,Lancaster, Simon
, p. 135 - 149 (2007/10/03)
Deprotonation of the phenol-imines 2-But-6- (RNCH)C6H3OH (R = 2,4,6-Me3C6H2 (1a), C6F5 (1b), C6H11 (1c) and phenolamines leads to the bis(ligand)
