415708-05-3Relevant academic research and scientific papers
A single-step emulsion approach to prepare fluorescent nanoscale coordination polymers for bioimaging
Sun, Zhiyong,Li, Yangxue,Guan, Xingang,Sun, Tingting,Chen, Li,Xie, Zhigang,Jing, Xiabin
, p. 14803 - 14806 (2014/04/17)
A crystalline nanoscale coordination polymer (NCP) based on fluorene and Zr4+ was synthesized through a simple microemulsion method. The emulsion method is facile and convenient for NCP production, the nanoparticles are fluorescent and thermal-
Nanoscale light-harvesting metal-organic frameworks
Zhang, Xuanjun,Ballem, Mohamed Ali,Hu, Zhang-Jun,Bergman, Peder,Uvdal, Kajsa
supporting information; experimental part, p. 5729 - 5733 (2011/08/07)
Highly crystalline nanoparticles of metal-organic frameworks with efficient light-harvesting properties were prepared by coordination-directed assembly (see picture). Functionalization of the ligands with long alkyl chains effectively stabilizes the nanoparticles and increases crystallinity. Different metal ions and ligands are organized into single nanoparticles and both organic acceptors and lanthanide ions can be co-sensitized within the frameworks. Copyright
Self-assembled multilayers of CdSe nanocrystals and carboxylate-handled phenylene-based molecules: Optical, electrochemical and photoconductive properties
Vercelli, Barbara,Zotti, Gianni,Berlin, Anna,Pasini, Mariacecilia,Natali, Marco
supporting information; experimental part, p. 8645 - 8652 (2012/01/15)
A series of linear phenylene-based molecules, bearing carboxylic acid or carboxylate functionalities at both ends, were reacted with (hexadecylamine/ stearate)-capped CdSe nanocrystals (7.5 nm diameter) dispersed in CHCl 3 to form multilayers on ITO-glass surfaces via layer-by-layer (LBL) alternation. The new multilayered materials were investigated by UV-Vis spectroscopy, cyclic voltammetry, photoelectrochemistry and photoconductivity. The conjugated linkers, with reversible reduction potentials in the range -1.7 to -2.8 V vs. Ag/Ag+, ease charge transport between dots (LUMO at -1.4 V). Photoconduction is dominated by interdot distance and linker characteristics rather than by LUMO energy levels. The logarithm of photoconductivity and linker length are linearly related, as in conduction of molecular wires, and the tunnelling attenuation factor β value is 2.4 nm-1. Comparison of n-type aromatics and p-type oligothiophenes is discussed.
Twin probes as a novel tool for the detection of single-nucleotide polymorphisms
Ergen, Erhan,Weber, Markus,Jacob, Josemon,Herrmann, Andreas,Muellen, Klaus
, p. 3707 - 3713 (2008/02/06)
Single-nucleotide polymorphisms (SNPs) are the most common form of DNA sequence variation. There is a strong interest from both academy and industry to develop rapid, sensitive and cost effective methods for SNP detection. Here we report a novel structura
