41577-83-7Relevant academic research and scientific papers
Conjugate addition of lithium diorganocuprate reagents to the enol tosylate of a 1,2-diketone
Charonnat,Mitchell,Keogh
, p. 315 - 318 (2007/10/02)
The conjugate addition of lithium diorganocuprate reagents to the enol tosylate of 1,2-cyclohexanedione has been investigated. The intermediate enolates eliminate para-toluenesulfinate ion to generate the alkylated 1,2-dicarbonyl system.
A New Synthesis of 3-Alkyl-1,2-cyclohexanediones from 2-Alkylcyclohexanones Using Iodine/Copper(II) Acetate
Horiuchi, C. Akira,Kiyomiya, Hiroshi,Takahashi, Masaaki,Suzuki, Yasuto
, p. 785 - 786 (2007/10/02)
The reactions of 2-alkyl-, 2,5-dimethyl-, and 3,3,5-trimethylcyclohexanone with iodine/copper(II) acetate in boiling aqueous acetic acid gave the respective 3-alkyl-, 3,6-dimethyl-, and 3,5,5-trimethyl-1,2-cyclohexanediones in 40-70percent yields.This new
