41597-25-5Relevant academic research and scientific papers
TMS·OTf-Catalyzed α-bromination of carbonyl compounds by N-bromosuccinimide
Guha, Samar Kumar,Wu, Bo,Kim, Beom Soo,Baik, Woonphil,Koo, Sangho
, p. 291 - 293 (2007/10/03)
Various carbonyl compounds undergo α-bromination reaction under a mild and practical condition utilizing N-bromosuccinimide (NBS), catalyzed by trimethylsilyl trifluoromethanesulfonate (TMS·OTf). This method is also effective for the side-chain bromination of heteroaromatic carbonyl compounds without the ring brominations.
CONVENIENT PREPARATION OF 1,2-CYCLOHEXANEDIONES
Utaka, Masanori,Matsushita, Seishiro,Takeda, Akira
, p. 779 - 780 (2007/10/02)
1,2-Cyclohexanedione and 3-alkyl-1,2-cyclohexanediones were prepared in good to excellent yields from the corresponding 2,6-dibromocyclohexanones by treatment with aqueous NaOH.
