416874-83-4Relevant academic research and scientific papers
Synthesis and crystal structure of a dinuclear palladium complex containing C,O-bridging ester-enolato moieties
Tian, Gonglu,Boyle, Paul D.,Novak, Bruce M.
, p. 1462 - 1465 (2008/10/08)
Palladium ester enolates have been prepared and characterized using IR, NMR, and single-crystal X-ray diffraction techniques. The X-ray diffraction established a dimeric crystal structure for complex {[N∧N]PdCH2C(O)OCH3}2 (N∧N = 1-[1-(5-methylpyrrole-2-yl)ethylidne]amino-2,6-diisopropylbenzene), 2, which contains C,O-bridging enolato groups. Upon reaction with donor molecules (acetonitrile, phosphines), the dimeric 2 cleaves to form monometallic C-bound enolate complexes, 3′ and 4.
