416892-92-7

Upstream product

• 768-33-2 phenyldimethylsilyl chloride 
• 18162-48-6 tert-butyldimethylsilyl chloride 

Downstream Products

• 1315303-20-8 C₂₁H₃₆O₂Si₂ 
• 1315303-19-5 (R)-1-(tert-butyldimethylsilyl)-3-(dimethyl(phenyl)silyl)prop-2-yn-1-ol 
• 1315302-86-3 1-(tert-butyldimethylsilyl)-3-(dimethyl(phenyl)silyl)prop-2-yn-1-one 
• 1315302-95-4 C₁₇H₂₈OSi₂ 
• 416893-73-7 (Z)-3-(tert-butyldimethylsiloxy)-1-(dimethyl-(phenyl)silyl)buta-1,3-diene 
• 207926-00-9 (Z)-1-(tert-butyldimethylsilyl)-3-(dimethyl(phenyl)silyl)-2-propen-1-one 

Relevant academic research and scientific papers

[3 + 2] annulation of β-heteroatom-substituted α,β-unsaturated acylsilanes with methyl ketone enolates: Scope and investigation of the reaction course

A new route to (Z)-β-silylacryloylsilanes 10 and the improved conditions for the [3 + 2] annulation using 10 and alkyl methyl ketone enolates are reported. Also, details of investigations defining a reaction course of the [3 + 2] annulation using β-phenylthio- and β-trimethylsilyl-acryloylsilanes 1 (X = SPh, SiMe3) and alkyl methyl ketone enolates are described.