4177-72-4Relevant academic research and scientific papers
A selective and convenient ruthenium mediated method for the synthesis of mixed acetals and orthoesters
Krompiec, Stanis?aw,Penczek, Robert,Ku?nik, Nikodem,Ma?ecki, Jan Grzegorz,Matlengiewicz, Marek
, p. 137 - 140 (2007/10/03)
Addition of alcohols and phenols to O-allyl compounds (allyl ethers and acrolein acetals), catalyzed by [RuCl2(PPh3)3], was examined. Intramolecular addition of an OH group, leading to the formation of cyclic acetals and o
Coating composition comprising a bicyclo- or spiro-orthoester functional compound
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, (2008/06/13)
The invention pertains to a coating composition comprising a first compound comprising at least one bicyclo- or spiro-orthoester group and a second compound comprising at least two hydroxyl-reactive groups. The invention also comprises a process for curing the present coating composition. More particularly, the latent hydroxyl groups of the bicyclo- or spiro-orthoester groups have to be deblocked and reacted with the hydroxyl-reactive groups of the second compound if the present coating composition is to be cured. Further, a process for making bicyclo-orthoester compounds from the corresponding oxetane compound is described, as are polymers comprising at least one bicyclo- or spiro-orthoester group.
