41780-70-5

Basic information

• Product Name: Benzenesulfonic acid,4-methyl-, 2-[5-methyl-2-(1-methylethyl)cyclohexylidene]hydrazide
• Synonyms: Benzenesulfonicacid, 4-methyl-, [5-methyl-2-(1-methylethyl)cyclohexylidene]hydrazide (9CI);NSC 132028
• CAS NO: 41780-70-5
• Molecular Formula: C17H26 N2 O2 S
• Molecular Weight: 322.472
• Mol File: 41780-70-5.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: Benzenesulfonic acid,4-methyl-, 2-[5-methyl-2-(1-methylethyl)cyclohexylidene]hydrazide(CAS DataBase Reference)
• NIST Chemistry Reference: Benzenesulfonic acid,4-methyl-, 2-[5-methyl-2-(1-methylethyl)cyclohexylidene]hydrazide(41780-70-5)
• EPA Substance Registry System: Benzenesulfonic acid,4-methyl-, 2-[5-methyl-2-(1-methylethyl)cyclohexylidene]hydrazide(41780-70-5)

Safety Data

• Hazardous Substances Data: 41780-70-5(Hazardous Substances Data)

Upstream product

• 491-07-6 (+/-)-menthone 
• 1576-35-8 toluene-4-sulfonic acid hydrazide 

Downstream Products

• 5256-65-5 2-menthene 

Relevant articles and documents

Hydrogen Participation vs. Elimination. The Role and Fate of Neighboring Hydrogen in Solvolysis of Neomenthyl Tosylate

Product composition and α-d1 and β-d3 isotope effects in the solvolysis of neomenthyl tosylate (8-OTs) were determined in 70 percent aqueous trifluoroethanol and 70 percent aqueous ethanol.Both trifluoroethanolysis and ethanolysis gave 1-2 percent neomenthol (97percent d3), 12-13percent cis-4-menthanol (100percent d3), 2-3percent trans-4-menthanol (100percent d3), 66-70percent 3-p-menthene (83percent d3 and 17percent d2), and 5-9percent 4,8-p-menthene (97percent d3), respectively.These results and the high value of the β-d3 isotope effect (kH/kD=2.45) were interpreted in terms of rate-determining hydride shift followed by elimination which accounts for 75percent of all products.In 85percent of the elimination productsthe migrating hydrogen (deuterium) is not the one being eliminated.