41795-35-1

Upstream product

• 132398-38-0 6-chloro-6-phenylsulfonyl-1-hexene 
• 193097-39-1 6-chloro-6-phenylsulfinyl-1-hexene 
• 125115-14-2 1-chloro-1-phenylsulfanyl-5-hexene 
• 39984-84-4 hex-5-en-1-yl(phenyl)sulfane 
• 112185-49-6 dimethyl 2-(pent-4-en-1-yl)malonate 
• 873-55-2 sodium benzenesulfonate 
• 2695-47-8 6-Bromo-1-hexene 

Downstream Products

• 1204323-01-2 C₂₉H₄₈O₄S 
• 1204322-98-4 C₂₆H₂₆O₄S 
• 1327155-40-7 C₂₃H₂₆O₄S 
• 1327155-52-1 C₂₈H₂₈O₄S 
• 1327155-42-9 C₁₈H₂₄O₄S 
• 1327155-54-3 C₂₃H₂₆O₄S 
• 1327155-41-8 C₂₂H₃₂O₄S 
• 1327155-53-2 C₂₇H₃₄O₄S 
• 1327155-44-1 C₁₈H₂₂O₂ 

Relevant academic research and scientific papers

SmI2 mediated reductive addition of bis-phenylsulfones to ketones

SmI2 mediates the in situ reductive addition of geminal bis- phenylsulfones to unhindered ketones at room temperature affording β- hydroxyphenylsulfones in good to excellent yields.

Use of Nitrogen-Doped Carbon Nanodots for the Photocatalytic Fluoroalkylation of Organic Compounds

The use of amine-rich N-doped carbon nanodots (NCNDs) for the photochemical radical perfluoroalkylation of organic compounds is reported. This operationally simple approach occurs under mild conditions producing valuable new C?C bonds. The chemistry is dr

Proline sulphonamide-catalysed Yamada-Otani condensation: Reaction development, substrate scope and scaffold reactivity

The development of a proline sulphonamide-catalysed method for enantioselective and diastereoselective construction of functionalized cyclohexenones is described. Impact of catalyst structure as well as solvent effects and additives are explored. A significant substrate scope is demonstrated by variation of both the aldehyde and the enone components. Diastereoselective derivatization of the cyclohexenone scaffold illustrates its utility as a building block for chemical synthesis.

Synthesis of all-carbon, quaternary center-containing cyclohexenones through an organocatalyzed, multicomponent coupling

Organocatalyzed multicomponent coupling using a new ester-containing, proline aryl sulfonamide has been developed for accessing densely functionalized cyclohexenones, each containing a quaternary center in high enantio- and diastereoselectivity. In contrast to most enamine/iminium-catalyzed reactions, the use of molecular sieves was critical to optimum enantioselectivity.

Generation and intramolecular cyclization of α-sulfinyl and α-sulfonyl radicals

α-Phenylsulfinyl and α-Phenylsulfonyl radicals are generated by the reactions of α-chlorosulfoxides and α-chlorosulfones with tributyltin hydride, respectively. High reaction concentration (0.2 M) is required to ensure efficient generations of these radic

The study of intramolecular free radical cyclizations of α-sulfonyl and α-sulfinyl radicals

α-Sulfonyl and α-sulfinyl radicals can be generated from the corresponding α-halosulfones and α-halosulfoxides. Our results indicate that these radicals cyclize very efficiently.