41796-37-6Relevant academic research and scientific papers
Dinuclear NHC Gold(I) Allenyl and Propargyl Complexes: An Experimental and Theoretical Study
Zargaran, Poorya,Mulks, Florian. F.,Gall, Samuel,Rudolph, Matthias,Rominger, Frank,Hashmi, A. Stephen K.
, p. 1524 - 1533 (2019)
The synthesis and isolation of the dinuclear NHC gold(I) allene-1,3-diyl complex Ph(IPrAu)C=C=CH(AuIPr) and the dinuclear NHC gold(I) propyne-1,3-diyl complex Ph(IPrAu)CH-C-C-Au(IPr) are presented. The monoprotodeauration reactions of these dinuclear comp
Polylithiumorganic compounds -21. On the Deproptonation of 1- and 3-Phenylpropyne as well as Phenylallene with Butyllithium. A Reinvestigation: Three Different Monoanions but one and the same Dianion
Maercker, Adalbert,Fischenich, Jakob
, p. 10209 - 10218 (2007/10/02)
In contrast to the literature, with butyllithium only one and the same dianion - namely 7 - is formed starting with each of the three hydrocarbons 1, 4, and 6.On the other hand, upon working at low temperature in tetrahydrofuran as the solvent we were able to detect the three corresponding monoanions 9, 15, and 16, most interestingly 15 and 16 at temperatures higher then -40 deg C show rearrangement with 1,3-hydrogen shift.
