41841-03-6Relevant academic research and scientific papers
Visible-light-induced C=C bond cleavage of enaminones for the synthesis of 1,2-diketones and quinoxalines in sustainable medium
Cao, Shuo,Zhong, Shanshan,Xin, Luoting,Wan, Jie-Ping,Wen, Chengping
, p. 1478 - 1482 (2015)
The C=C double bond cleavage of enaminones has been realized under ambient conditions through visible-light catalysis in the presence of Rose Bengal, which leads to the synthesis of a class of 1,2-diketones without using any metal catalyst. In addition, the one-pot synthesis of quinoxalines has also been achieved under identical photocatalytic conditions by making use of the in situ generated 1,2-diketones as intermediates.
