41860-70-2Relevant academic research and scientific papers
Copper(II)-catalyzed O-phenylation of tertiary alcohols with organobismuth(V) reagents
Ikegai, Kazuhiro,Fukumoto, Kentarou,Mukaiyama, Teruaki
, p. 612 - 613 (2006)
A new method for the Cu(OAc)2-catalyzed phenylation of tertiary alcohols under mild basic conditions is described. Triphenylbismuth(V) diacetate and tetraphenylbismuth reagents undergo cross-coupling reactions with α-hydroxycarbonyl compouds efficiently. For non-chelating tertiary alcohols, tetraphenylbismuth fluoride is found suitable as a phenyl donor. Copyright
