418753-56-7

Upstream product

• 76369-27-2 (Z)-3-Ethylamino-3-methylsulfanyl-1-phenyl-propenone 
• 13636-88-9 3,3-bis(methylthio)-1-phenylprop-2-en-1-one 
• 94153-62-5 ethyl 2-diazo-3-[(trimethylsilyl)oxy]but-3-enoate 
• 213180-53-1 (E)-3-(ethylamino)-3-(thiomethyl)-1-phenylprop-2-ene-1-thione 

Relevant academic research and scientific papers

Facile synthesis of 4-alkyl (and aryl)-2-aryl-6-diazo-4H-thieno[3,2-b] pyridine-5,7-diones

Treatment of 3-{3-alkyl (and aryl)amino-5-arylthieno-2-yl}-2-diazo-3- oxopropanoates 8 with TMSOTf (3 equiv) in the presence of Et3N (6 equiv) in CH2Cl2 for 1 h at room temperature afforded 4-alkyl (and aryl)-2-aryl-6-diazo-4H-thieno

Novel synthesis of 5,6-dihydro-4H-thieno[3,2-b]pyrrol-5-ones via the rhodium(II)-mediated Wolff rearrangement of 3-(thieno-2-yl)-3-oxo-2-diazopropanoates

(equation presented) Treatment of thioaryolketene S,N-acetals 12 with Hg(OAc)2 followed by addition of 2-diazo-3-trimethylsilyloxy-3-butenoic acid alkyl esters 15 in CH2Cl2 at room temperature gave 3-(3-alkylamino-5-arylth