418760-99-3Relevant articles and documents
Synthesis of 6-methyl-4-(1-methyl-2-buten-1-yl)-2-(2-cyclohexen-1-yl)- and 6-methyl-4-(1-methyl-2-buten-1-yl)-2-(1-cyclohexen-1-yl)anilines
Gataullin,Ishberdina,Sotnikov,Abdrakhmanov
, p. 438 - 440 (2005)
Alkenylation of 6-methyl-2-(2-cyclohexen-1-yl)- and 2-(1-cyclohexen-1-yl)anilines with piperylene in the presence of AlCl 3 and transformation of the resulting cyclohexenylanilines into carbazole structures were studied.
Functiaonalization of 2-(1-Cyclohexen-1-yl)aniline Derivatives
Khusnitdinov,Sultanov,Gataullin
, p. 653 - 662 (2019/06/05)
The reaction of 2-(1-cyclohexen-1-yl)aniline and -6-methylaniline with phthalic anhydride has afforded 2-(2-cyclohex-1-en-1-ylphenyl)- and 2-(2-cyclohex-1-en-1-ylphenyl)-6-methylphenyl)-1H-isoindole-1,3(2H)-diones. The reaction of the obtained isoindole-1,3-diones with bromine in dichloromethane in the presence of sodium bicarbonate has led to the formation of the product of pseudo-allylic halogenation. Replacement of the halogen atom by methoxy group has been performed by keeping 2-[2-(6-bromocyclohex-1-en-1-ylphenyl)-6-methylphenyl)]-1H-isoindole-1,3(2H)-dione in a methanolic solution in the presence of NaHCO3. The reaction of 2-(2-cyclohex-1-en-1-yl-6-methylphenyl)-1H-isoindole-1,3(2H)-dione with molecular bromine in the presence of methanol has given a co-halogenation product, whereas the dibromination product has been obtained in the presence of octyl alcohol.
