41881-06-5Relevant academic research and scientific papers
Dioxolanylium Ions Derived from Carbohydrates. VI. Rearrangement of Derivatives of α- and β-Galactopyranosides and Their Reaction with Nucleophiles
Jacobsen, Steffen,Mols, Ole
, p. 163 - 168 (2007/10/02)
The position of the equilibrium 2->/-3 for a number of 2-phenyl-1,3-dioxolanylium ions, fused to carbohydrates of the galacto and gulo configuration, has been measured in acetonitrile solution.THe anomeric configuration was found to influence both the position of the equilibrium between the benzoxonium ions and the outcome of the trans-opening of the benzoxonium ions with bromine ion.
