41881-84-9Relevant academic research and scientific papers
Photoredox-Mediated Direct Cross-Dehydrogenative Coupling of Heteroarenes and Amines
Dong, Jianyang,Xia, Qing,Lv, Xueli,Yan, Changcun,Song, Hongjian,Liu, Yuxiu,Wang, Qingmin
supporting information, p. 5661 - 5665 (2018/09/21)
A photoredox-mediated direct cross-dehydrogenative coupling reaction to accomplish α-aminoalkylation of N-heteroarenes is reported. This mild reaction has a broad substrate scope, offers the first general method for synthesis of aminoalkylated N-heteroarenes without the need for substrate prefunctionalization, and is scalable to the gram level. Furthermore, the reaction was found to be applicable to other hydrogen donors besides amines (i.e., ethers, an aldehyde, a formamide, p-xylene, and alkanes), thus enabling the preparation of N-heteroarenes bearing various types of substituents.
Peroxides as "switches" of dialkyl H-phosphonate: Two mild and metal-free methods for preparation of 2-acylbenzothiazoles and dialkyl benzothiazol-2-ylphosphonates
Chen, Xiao-Lan,Li, Xu,Qu, Ling-Bo,Tang, Yu-Chun,Mai, Wen-Peng,Wei, Dong-Hui,Bi, Wen-Zhu,Duan, Li-Kun,Sun, Kai,Chen, Jian-Yu,Ke, Dian-Dian,Zhao, Yu-Fen
, p. 8407 - 8416 (2015/03/18)
Two mild and metal-free methods for the preparation of two kinds of important benzothiazole derivatives, 2-acylbenzothiazoles and dialkyl benzothiazol-2-ylphosphonates, respectively, were developed. The dialkyl H-phosphonate (RO)2P(O)H exists i
