41882-15-9Relevant articles and documents
One-pot synthesis of amides via the oxidative amidation of aldehydes and amines catalyzed by a copper-MOF
Jamalifard, Samira,Mokhtari, Javad,Mirjafary, Zohreh
, p. 22749 - 22754 (2019/08/01)
An efficient method for the oxidative amidation of aldehydes with primary aromatic and aliphatic amines has been developed for the synthesis of a wide variety of amides using inexpensive Cu2(BDC)2DABCO (Cu-metal-organic framework [MOF]) as a recyclable heterogeneous catalyst, and N-chlorosuccinimide and aqueous tert-butyl hydroperoxide as oxidants in acetonitrile. This amidation reaction is operationally straightforward and provides secondary amides in good yields in most cases, utilizing inexpensive and readily available reagents under mild conditions.
Complexes of silicon and phosphorus chlorides with nitrogen-containing bases as the condensing agents in the synthesis of amides
Besgubenko, L. V.,Pipko, S. E.,Sinitsa, A. D.
, p. 1382 - 1390,9 (2020/09/16)
High effectiveness of new condensing agents on the basis of complexes of silicon and phosphorus chlorides with nitrogen-containing bases in the synthesis of amides from carboxylic acids and amines and also in heterocyclization is shown. Factors affecting the readiness of formation of the amide bond and the yields of the final products are established.