419562-69-9

Basic information

• Product Name: CH₃C₅H₃Mn(CO)3B(C₃H₂CH₂C₆H₁₁N₂)3^(1-)*Tl⁽¹⁺⁾=CH₃C₅H₃Mn(CO)3B(C₃H₂CH₂C₆H₁₁N₂)3Tl
• CAS NO: 419562-69-9
• Molecular Weight: 922.004
• Mol File: 419562-69-9.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: CH₃C₅H₃Mn(CO)3B(C₃H₂CH₂C₆H₁₁N₂)3^(1-)*Tl⁽¹⁺⁾=CH₃C₅H₃Mn(CO)3B(C₃H₂CH₂C₆H₁₁N₂)3Tl(CAS DataBase Reference)
• NIST Chemistry Reference: CH₃C₅H₃Mn(CO)3B(C₃H₂CH₂C₆H₁₁N₂)3^(1-)*Tl⁽¹⁺⁾=CH₃C₅H₃Mn(CO)3B(C₃H₂CH₂C₆H₁₁N₂)3Tl(419562-69-9)
• EPA Substance Registry System: CH₃C₅H₃Mn(CO)3B(C₃H₂CH₂C₆H₁₁N₂)3^(1-)*Tl⁽¹⁺⁾=CH₃C₅H₃Mn(CO)3B(C₃H₂CH₂C₆H₁₁N₂)3Tl(419562-69-9)

Safety Data

• Hazardous Substances Data: 419562-69-9(Hazardous Substances Data)

Upstream product

• 61649-79-4 methylcymantrenyl(3-dibromo)borane 
• 73123-54-3 4-(cyclohexyl)methylpyrazole 
• 20398-06-5 thallium (I) ethoxide 

Relevant articles and documents

Tl(I) complexes of cymantrene-based tris(1-pyrazolyl)borates: Polymers and macrocycles

Cymantrene-based tris(1-pyrazolyl)borates have been synthesised from the reaction of CymBBr2 and Cym'BBr2 with pyrazole (Hpz) in the presence of triethylamine [Cym: cymantrenyl; Cym': (methyl)cymantrenyl]. The Tl(I) salts CymB(pz)3Tl,2a, and Cym'B(pz)3Tl,2b, have been structurally characterised by X-ray crystallography. Similar to the corresponding complex FcB(pz)3Tl (Fc: ferrocenyl), CymB(pz)3Tl features a polymeric structure with bridging [B(pz)3] fragments in the solid state. Cym'B(pz)3Tl shows a related oligomeric structure. This time a macrocyclic tetramer rather than a linear chain is observed. To provide a ligand of high solubility in non-polar solvents, compound Cym'B(pz4-R)3Tl, [R = CH2(C6H11)]2d, has been synthesised, which shows a reduced symmetry at the organometallic moiety, together with (cyclohexyl)methyl substituents in the 4-positions of all pyrazolyl rings.