4198-64-5

Basic information

• Product Name: 1H-Benzimidazole,2-[2-(methylthio)ethyl]-(9CI)
• Synonyms: 1H-Benzimidazole,2-[2-(methylthio)ethyl]-(9CI)
• CAS NO: 4198-64-5
• Molecular Formula: C10H12N2S
• Molecular Weight: 192.28068
• Product Categories: BENZIMIDAZOLE
• Mol File: 4198-64-5.mol
• Article Data: 1

Chemical Properties

• Appearance: /
• CAS DataBase Reference: 1H-Benzimidazole,2-[2-(methylthio)ethyl]-(9CI)(CAS DataBase Reference)
• NIST Chemistry Reference: 1H-Benzimidazole,2-[2-(methylthio)ethyl]-(9CI)(4198-64-5)
• EPA Substance Registry System: 1H-Benzimidazole,2-[2-(methylthio)ethyl]-(9CI)(4198-64-5)

Safety Data

• Hazardous Substances Data: 4198-64-5(Hazardous Substances Data)

Upstream product

• 646-01-5 3-(methylsulfanyl)propionic acid 
• 95-54-5 1,2-diamino-benzene 

Relevant articles and documents

Neighboring-Group Participation in Organic Redox Reactions. 10. The Kinetic and Mechanistic Effects of Imidazole and Benzimidazole Nitrogen on Thioether Oxidations

The kinetics of the aqueous iodine oxidation of a number of imidazolyl- and benzimidazolylalkyl methyl sulfides have been studied.Evidence of neighboring-group participation has been observed in all cases.The anchimeric assistance provided by the benzimidazole moiety is evidenced by rate accelerations of 102-105.The oxidation of 1-methyl-2-imidazole, 1, is 106 times faster than that of simple thioethers and is faster than any previously reported acyclic thioether.The reaction of 2-benzimidazole is accelerated by105 via a transient N-S dication.Additionally, the pH profiles of all of the compounds studied provide strong evidence for N-S interacted intermediates.