41996-95-6Relevant academic research and scientific papers
In situ coupled oxidation cycle catalyzed by highly active and reusable Pt-catalysts: Dehydrogenative oxidation reactions in the presence of a catalytic amount of o-chloranil using molecular oxygen as the terminal oxidant
Miyamura, Hiroyuki,Maehata, Kanako,Kobayashi, Shu
supporting information; experimental part, p. 8052 - 8054 (2011/01/03)
An in situ coupled oxidation cycle that allows catalytic oxidation of a substrate with catalytic amounts of o-chloranil and novel reusable polymer-immobilized platinum nanocluster catalysts using molecular oxygen as the terminal oxidant was developed.
Self-limiting robust surface-grafted organic nanofilms
Todd Banner,Tekobo, Samuel,Garay, Fernando,Clayton, Benjamin T.,Thomas, Zachary P.,Lindner, Ernoe,Richter, Andrew G.,Pinkhassik, Eugene
, p. 2248 - 2254 (2011/11/30)
Robust surface-bound insulating polymer films with controlled thickness in 5 nm range are important for technological advances in diverse disciplines such as electrochemical sensors, molecular electronics, separations, and anticorrosive coatings. Creatin
Nanothin polymer coatings containing thiol and methods of use thereof
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, (2010/12/29)
The present invention provides a new monomer and methods of using the monomer to fabricate robust polymer surface coatings with controlled thicknesses between 1 and 5 nanometers. The coatings are composed of a new material containing polymerized monomers of 4-vinylbenzenepropanethiol. The polymer surface coating may be applied to metal and silicon. The method includes exposing a metal substrate to a solution of the monomer in hexanes in order to deposit a monolayer of the monomer onto the metal surface. The substrate is then irradiated with ultraviolet radiation in order to graft a thin polymer coating onto the surface. The procedure can be repeated in order to control the thickness of the coating between about 1 nm and 5 nm. Alternatively, thermally initiated polymerization or deposition of partially oligomerized monomers onto the surface provides nanothin coatings with identical performance. The coating provides complete surface coverage, is extremely robust, and exhibits excellent insulating and anti-corrosive properties.
General access to para-substituted styrenes
Langle, Sandrine,David-Quillot, Franck,Balland, Alexia,Abarbri, Mohamed,Duchêne, Alain
, p. 113 - 119 (2007/10/03)
A simple and efficient procedure has been developed for the synthesis of organogermanium compounds and styrenes para-substituted with groups containing an atom of the 14th group by one-pot reaction of halogenosilanes, germanes or stannanes, organic halides and magnesium using ultrasound methods.
General access to para-substituted styrenes
Langle, Sandrine,David-Quillot, Franck,Balland, Alexia,Abarbri, Mohamed,Duchêne, Alain
, p. 113 - 119 (2015/03/05)
A simple and efficient procedure has been developed for the synthesis of organogermanium compounds and styrenes para-substituted with groups containing an atom of the 14th group by one-pot reaction of halogenosilanes, germanes or stannanes, organic halides and magnesium using ultrasound methods.
