42044-65-5

Basic information

• Product Name: 2,3-Dimethyl-2-phenylbuttersaeurechlorid
• CAS NO: 42044-65-5
• Molecular Weight: 210.704
• Mol File: 42044-65-5.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: 2,3-Dimethyl-2-phenylbuttersaeurechlorid(CAS DataBase Reference)
• NIST Chemistry Reference: 2,3-Dimethyl-2-phenylbuttersaeurechlorid(42044-65-5)
• EPA Substance Registry System: 2,3-Dimethyl-2-phenylbuttersaeurechlorid(42044-65-5)

Safety Data

• Hazardous Substances Data: 42044-65-5(Hazardous Substances Data)

Upstream product

• 29936-67-2 2,3-Dimethyl-2-phenylbutannitril 
• 60902-63-8 2,3-dimethyl-2-phenyl-butyric acid amide 
• 492-37-5 hydratropic acid 
• 140-29-4 phenylacetonitrile 
• 5558-29-2 3-methyl-2-phenyl-butyronitrile 

Downstream Products

• 60902-65-0 (±)-2,3-dimethyl-2-phenylbutan-1-ol 
• 60902-66-1 2,3-Dimethyl-2-phenylbutylessigsaeureester 
• 60902-62-7 2,3-Dimethyl-2-phenylbuttersaeure-phenylester 
• 22876-56-8 1,2-dimethyl-1-phenyl-propylamine 
• 51556-26-4 2,3-Dimethyl-2-phenylbutylmethylketon 
• 42044-36-0 2,3-Dimethyl-2-phenyl-butaneperoxoic acid tert-butyl ester 
• 60902-61-6 2,3-Dimethyl-2-phenylbuttersaeure-methylester 

Relevant articles and documents

Palladium(II)-Catalyzed C(sp2)-H Bond Activation/C-N Bond Cleavage Annulation of N-Methoxy Amides and Arynes

The Pd(II)-catalyzed C-H bond activation/C-N bond cleavage annulation reaction of N-alkyoxyamide aryne is developed to synthesize 9,10-dihydrophenanthrenone derivatives. This reaction exhibited good functional group compatibility with yields up to 92%. Detailed mechanistic studies showed that the key to C-N bond cleavage is the formed eight-membered palladacycle intermediate undergoing nucleophilic addition to the carbonyl group, which provides a new and practical way for N-alkoxyamide directed C-H bond activation.