42053-93-0Relevant academic research and scientific papers
Highly regioselective and chemoselective titanocene mediated Barbier-type allylation reactions
Morcillo, Sara P.,Martinez-Peragon, Angela,Jakoby, Verena,Mota, Antonio J.,Kube, Christian,Justicia, Jose,Cuerva, Juan M.,Gansaeuer, Andreas
supporting information, p. 2211 - 2213 (2014/02/14)
Titanocene carboxylate 1 is an excellent chemoselective reagent for unprecedented α-regioselective Barbier-type reactions. It constitutes the first titanocene(iii) able to tolerate epoxides and readily reduced carbonyl compounds, such as aromatic and α,β-unsaturated aldehydes. The Royal Society of Chemistry.
Nanostructured styrenic co-polymers containing glucopyranosyl residues and their functionalization
Pocci, Marco,Alfei, Silvana,Lucchesini, Francesco,Bertini, Vincenzo,Idini, Barbara
experimental part, p. 5684 - 5692 (2009/12/03)
Sugar-based co-polymers with saccharidic units in stable cyclic form and nanometric morphologies stabilized through crosslinking, adaptable through specific functionalizations to biochemical interaction studies with copper-containing amine oxidases, were synthesized from appropriate monomers and macromonomers. The most promising nanospherical co-polymer obtained, containing β-d-glucopyranosidic units, was employed in functionalization reactions with the help of model molecules, achieving useful transformations mainly at the 6-position and to a minor extent at the 2-position of the saccharidic system.
