4208-31-5Relevant academic research and scientific papers
Synthesis and metal complexes of symmetrically N-substituted bispidinones
Black, David St. C.,Deacon, Glen B.,Rose, Michael
, p. 2055 - 2076 (2007/10/02)
The symmetrically substituted bispidinones (9-23) were prepared by the Mannich reaction. The bispidinone (28) can be used to generate the diaminoethyl derivative (25) and the diphenoxy ether (32). The crystal structure of the glycinic bispidinone (20) is reported. Metal complexes of bispidinones (4), (35-54) were prepared with copper, palladium and platinum.
Conformational Control in the 3,7-Diazabicyclononane System
McCabe, P. H.,Milne, N. J.,Sim, G. A.
, p. 625 - 626 (2007/10/02)
The twin-chair or boat-chair conformation of 3,7-diazabicyclononanes can be selected by forming N,N'-derivatives in which the N atoms have planar or pyramidal bonding patterns, respectively, e.g., acyl substituents for the former and arylsulphonyl
