42117-07-7

Basic information

• Product Name: ethyl 2-fluoro-3,3-diphenylprop-2-enoate
• CAS NO: 42117-07-7
• Molecular Weight: 270.303
• Mol File: 42117-07-7.mol
• Article Data: 2

Chemical Properties

• CAS DataBase Reference: ethyl 2-fluoro-3,3-diphenylprop-2-enoate(CAS DataBase Reference)
• NIST Chemistry Reference: ethyl 2-fluoro-3,3-diphenylprop-2-enoate(42117-07-7)
• EPA Substance Registry System: ethyl 2-fluoro-3,3-diphenylprop-2-enoate(42117-07-7)

Safety Data

• Hazardous Substances Data: 42117-07-7(Hazardous Substances Data)

Upstream product

• 119-61-9 benzophenone 
• 2356-16-3 ethyl(diethylphosphono)(fluoro)acetate 
• 100-58-3 phenylmagnesium bromide 
• 171916-53-3 triethyl 2-fluoro-3-oxo-2-phosphono-3-phenylpropanoate 
• 42117-03-3 C₁₀H₁₀BrFHgO₂ 
• 1450-31-3 Thiobenzophenon 

Downstream Products

• 15052-21-8 2-fluoro-3,3-diphenylprop-2-enoic acid 
• 1959-48-4 (2-bromo-2-fluoroethene-1,1-diyl)dibenzene 

Relevant articles and documents

Low-temperature 19F NMR spectroscopy of 1-fluoro-1-lithioethenes - Stability, shifts and unexpected coupling constants

Half-lives and fluorine atom shifts of stabilized 1-fluoro-l-lithioethenes bearing hydrogen, fluorine, phenyl, and/or dimethylphenylsilyl groups in the β-positions have been determined by a low-temperature 19F NMR spectroscopy. Some 1-fluoro-1-lithioethenes displayed an exceptionally low value of the trans-3JFF coupling constant. Stereoselectivity of carbenoid formation, as well as an effect of configuration on the stability is discussed.