42125-17-7

Basic information

• Product Name: HEX-4-ENYLACETATE
• Synonyms: HEX-4-ENYLACETATE;(Z)-4-Hexen-1-ol acetate;Acetic acid (Z)-4-hexen-1-yl ester;Acetic acid (Z)-4-hexenyl ester;(E)-4-hexen-1-yl acetate
• CAS NO: 42125-17-7
• Molecular Formula: C₈H₁₄O₂
• Molecular Weight: 142.2
• Mol File: 42125-17-7.mol
• Article Data: 5

Chemical Properties

• Appearance: /
• CAS DataBase Reference: HEX-4-ENYLACETATE(CAS DataBase Reference)
• NIST Chemistry Reference: HEX-4-ENYLACETATE(42125-17-7)
• EPA Substance Registry System: HEX-4-ENYLACETATE(42125-17-7)

Safety Data

• Hazardous Substances Data: 42125-17-7(Hazardous Substances Data)

Upstream product

• 920-39-8 isopropylmagnesium bromide 
• 5048-26-0 5-hexenyl acetate 
• 1608-67-9 2-acetoxytetrahydrofuran 
• 1530-32-1 ethyltriphenylphosphonium bromide 
• 7318-67-4 cis-1,4-hexadiene 
• 110-87-2 3,4-dihydro-2H-pyran 
• 75-16-1 methylmagnesium bromide 
• 108-24-7 acetic anhydride 
• 928-91-6 (Z)-4-hexenol 

Downstream Products

• 132646-21-0 3-carbonyl>amino>-4(E)-hexen-1-ol 
• 129966-08-1 C₂₁H₂₉NO₅S 
• 129966-08-1 C₂₁H₂₉NO₅S 

Relevant articles and documents

A stereospecific synthesis of 1,2-disubstituted homopropargylic protected alcohols from bromoallenols

Bromoallenols derived from propargylic epoxides are transformed in two steps and in a stereospecific fashion into 1,2-disubstituted homopropargylic protected alcohols with Grignard reagents with or without copper salts.

An alternative mechanism for the cobalt-catalyzed isomerization of terminal alkenes to (Z)-2-alkenes

The cobalt-catalyzed selective isomerization of terminal alkenes to the thermodynamically less-stable (Z)-2-alkenes at ambient temperatures takes place by a new mechanism involving the transfer of a hydrogen atom from a Ph2PH ligand to the starting material and the formation of a phosphenium complex, which recycles the Ph2PH complex through a 1,2-H shift.

Transformation of Carbon-Oxygen into Carbon-Carbon Bonds Mediated by Low-Valent Nickel Species

The substitution of alkoxy groups of enol ethers (1-methoxycyclohexenes, 1-methoxy-1-alkenes, and benzofuran) and aryl ethers (methoxynaphthalenes, cresyl methyl ethers, and dimethoxybenzenes) by hydrogen, alkyl groups, and aryl units, through Grignard reactions catalyzed by bis(triphenylphosphine)nickel dichloride or nickel dichloride, is described.The stereochemistry of the new reaction is portrayed, especially in connection with processes involving ring opening of dihydropyrans and dihydrofurans.The reaction has been applied to the synthesis of a termite trail pheromone and the acetate of the Douglas fir beetle aggregation pheromone.