42157-95-9Relevant articles and documents
Nucleophilicity parameters for carbanions in methanol
Thanh, Binh Phan,Mayr, Herbert
, p. 2530 - 2537 (2006)
The kinetics of the reactions between eleven carbanions 2a-k (nitronates and malonic acid derivatives) and benzhydrylium ions 1a-g were investigated photometrically in methanol/acetonitrile (91:9, v/v) at 20°C. Since the competing reactions of the benzhyd
Scalable, easy synthesis, and efficient isolation of arylnitromethanes: a revival of the Victor Meyer reaction
Alaime, Thibaud,Delots, Audrey,Pasquinet, Eric,Suzenet, Franck,Guillaumet, Gérald
, p. 1337 - 1341 (2017/01/21)
A modified approach to synthesize and isolate arylnitromethanes is described. The method takes advantage of the significant difference in acidity between the arylnitromethane and the major impurity of the reaction, the nitrite ester. The arylnitromethanes resulting from this process are obtained in high yields and are analytically pure, i.e., they do not require distillation or further purification, which is a comfortable improvement of the ancestral Victor Meyer reaction.
Nucleophilicities of nitroalkyl anions
Bug, Thorsten,Lemek, Tadeusz,Mayr, Herbert
, p. 7565 - 7576 (2007/10/03)
The kinetics of the reactions of eight nitroalkyl anions (nitronate anions) with benzhydrylium ions and quinone methides in DMSO and water were investigated photometrically. The second-order rate constants were found to follow a Ritchie constant selectivi
